Erg, posted this on DPR. Pretty much along the same lines as Chris' suggestions.
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Rotate clockwise 5-ish degrees to even out the face. 3:2 crop, eye placed at a good spot, kept hair for framing and use net/hand as diagonal. Slight level to up the exposure, curve for contrast. Separate level and curve to bring out the eye. Dodge & burn, USM, save for web.